Research Programs
IRG 3: Soft Cellular Materials

"Soft Cellular Materials", such as closed-cell polymer foams and high internal phase emulsions, are a versatile class of materials that are familiar in a wide variety of applications including barrier coatings, insulators, structural materials, super-absorbents, lotions and creams, processed foods, and advanced tissue scaffolds.

The recent availability of many new types of polymeric surfactants (e.g. block and graft copolymers) and functional nanoparticles creates exciting opportunities for novel structures, properties, and functions within this important class of materials. IRG-3 seeks to understand the interactions of surface-modified nanoparticles and new interfacially-active copolymers with polymeric interfaces and thin films, both in and out of equilibrium, and to apply this understanding to the development of innovative polymer-based, cellular materials.

The soft cellular materials relevant to our research include:

Closed-cell polymer foams

High internal phase polymeric emulsions (poly-HIPE)

Fluid precursors to the above

Compositions containing tunable nanoparticles and structured colloids

IRG MEMBERS:

Glenn Fredrickson (Co-leader) Chemical Engineering and Materials Mesoscopic & polymer theory
Gary Leal (Co-leader) Chemical Engineering and Materials Fluids experiment & theory
Craig Hawker Materials and Chemistry & Biochemistry Polymer & particle synthesis
Bud Homsy Mechanical Engineering and Chemical Engineering Fluids & stability theory
Jacob Israelachvili Chemical Engineering and Materials and BMSE Interfacial & surface force analysis
Ed Kramer Materials and Chemical Engineering Interfacial analysis, polymer physics
Jim Langer Physics and Materials Condensed matter theory, plasticity
Todd Squires Chemical Engineering Fluid physics, colloid microfluidics

IRG AFFILIATE:

Dave Pine NYU, Physics Complex fluids & colloid physics

TEM of 4nm Au nanoparticles localized (a) at the interface; and (b) in the PS domain of a PS-PVP diblock copolymer (PVP stained with I2).